Alkylation of active methylene compounds with alcohols catalyzed by an iridium complex.

نویسندگان

  • Masao Morita
  • Yasushi Obora
  • Yasutaka Ishii
چکیده

Base-free catalytic alpha-alkylation of active methylene compounds with primary alcohols was successfully achieved using an [IrCl(cod)](2) complex in the presence of PPh(3) to afford the corresponding saturated alpha-alkylated products in good yields.

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عنوان ژورنال:
  • Chemical communications

دوره 27  شماره 

صفحات  -

تاریخ انتشار 2007